高温尼龙PPA/PA6T全称聚对苯二甲酰己二胺,ARLEN™为日本三井化学公司(MitsuiChemicals,Inc)所开发出的一种耐热性尼龙6T/66,是一种PA6T与PA66共聚的产物。其电子零件用的PA6T/66为一种基于对苯二甲酸,己二酸及己二胺的改质尼龙6T,其熔点高达310℃。PA6T/66的主要特性为的高温刚性,尺寸安定性以及耐化学品性。的特性使PA6T在许多领域包括汽车零件,机械零件以及电气/电子零件上有广泛的应用。以下用PA6T泛指PA6T/66。
1. 的耐焊接性 PA6T具有很高的熔点(310℃),其热变形温度也很高(约290℃),因此可显现的耐焊接性(reflowsolderability)。的耐焊接性使PA6T特别适用于表面黏着技术(SMT)用电子连接器。
2.优良的高温刚性 PA6T在高温下仍可维持相当高的模数,譬如说在120℃时的模量为23℃时模量的55%。也就是说PA6T在广泛温度范围间可维持稳定而且优良的刚性。
3.优良的耐化学品性
4. 吸水率低 对于尼龙树脂而言,PA6T的吸水率相当低,仅为尼龙66的1/4至1/3。因此,PA6T因吸水所造成的物性变化相对较小。
5.优良的尺寸稳定性 PA6T的吸水率相当低,因吸水而造成的尺寸变化相当小。PA6T的热膨胀系数相当稳定,在高温范围中仍然维持在相当低的水准,因此,对温度变化的尺寸稳定性良好。此外,PA6T因成型过程所造成翘曲很小。也就是说PA6T具有优良的尺寸稳定性。
6. 优良的流动性 PA6T具有良好的熔融流动性,很容易以射出成型来加工。此外,PA6T还具有优良的薄壁成型性,使其适于小零件的加工成型。
High-temperature nylon PPA/PA6T, full name of poly (phthaloylhexanediamine), ARLEN&# 8482; A heat-resistant nylon 6T/66developed by Mitsui Chemicals, Inc. is a product of PA6T and PA66copolymerization. The PA6T/66 used for its electronic parts is amodified nylon 6T based on terephthalic acid, adipic acid andadipic acid, with a melting point of 310 ℃. The maincharacteristics of PA6T/66 are high temperature rigidity,dimensional stability and chemical resistance. The characteristicsof PA6T make it widely used in many fields, including automotiveparts, mechanical parts and electrical/electronic parts. PA6T isgenerally referred to as PA6T/66.
1. The welding resistance of PA6T has a high melting point (310℃), and its thermal deformation temperature is also high (about 290℃), so it can show the welding resistance. The solderability ofPA6T makes it particularly suitable for electronic connectors forsurface adhesion technology (SMT).
2. The excellent high-temperature rigid PA6T can still maintaina relatively high modulus at high temperature, for example, themodulus at 120 ℃ is 55% of the modulus at 23 ℃. That is to say,PA6T can maintain stability and excellent rigidity in a widetemperature range.
3. Excellent chemical resistance
4. Low water absorption For nylon resin, the water absorption ofPA6T is very low, only 1/4 to 1/3 of that of nylon 66. Therefore,the physical property change of PA6T caused by water absorption isrelatively small.
5. Excellent dimensional stability The water absorption of PA6Tis quite low, and the size change caused by water absorption isquite small. The thermal expansion coefficient of PA6T is , and it still remains at a relatively low level in the hightemperature range. Therefore, it has good dimensional stabilityagainst temperature changes. In addition, the warpage of PA6Tcaused by the forming process is very small. That is to say, PA6Thas excellent dimensional stability.
6. Excellent fluidity PA6T has good melt fluidity and is easy tobe processed by injection molding. In addition, PA6T also hasexcellent thin-wall formability, making it suitable for theprocessing and forming of small parts.